Can you use with electric straighteners?

Yes, but I would suggest something else that's strictly for heat protection, I use this usually after hair straightened as a frizz tamer

Is it basically a silicone coating in hair?

I don't feel that it is. This serum is perfect for curly frizzy hair. It smells great, holds hair well, no greasiness and is super shiny.

i am not sure about tbis product being vegan.

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GIOVANNI 2chic Ultra-Luxurious Super Potion Silkening Hair Serum - Cherry Blossom & Rose Petals, Aloe Vera, Pro-Vitamin B5, Smooths Curly & Wavy Hair, Paraben Free, Color Safe - 2.75 oz

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